Tuesday, April 12, 2011
Wednesday, April 6, 2011
Tuesday, April 5, 2011
Bengkel Teknik Menjawab Soalan Kimia SK027 photos (25 Mac 2011)
Monday, April 4, 2011
Organic Chemistry Workshop Photos ( 4 April 2011)
Friday, April 1, 2011
Benzene
Chlorination of benzene is different from the chlorination of methane.
a) State the type of reaction for chlorination of benzene.
b) Write the mechanism.
Alkene
Dehydration of 2-methylcyclohexanol with concentrated sulphuric acid yields a mixture of three alkenes. Draw all the structure of alkenes and suggest the major product . Propose the mechanism of its formation
Chemistry Organic Workshop
TASK 3 ( Mechanism & Predict Structure)
1 | Dehydration of 2-methylcyclohexanol with concentrated sulphuric acid yields a mixture of three alkenes. Draw all the structure of alkenes and suggest the major product . Propose the mechanism of its formation | |||
2 | Two organic compounds, A and B have a similar molecular formula, C4H9Cl. Both compounds react with sodium hydroxide aqueous solution to form C and D with molecular formula C4H10Cl via SN1 and SN2 mechanisms respectively. Draw the structure of A, B, C and D. Write a mechanism for the formation of D. | |||
3 | Chlorination of benzene is different from the chlorination of methane. a) State the type of reaction for chlorination of benzene. b) Write the mechanism. | |||
4 | A few organic compounds represented by the letters P to S are shown below: Which of the above compounds will; a) form an ester when it reacts with ethanol? b) decolorised hot acidified KMnO4? c) form silver mirror when it reacts with Tollen's reagent? | |||
5 | Both P (C2H4O) and Q (C2H6O) react similarly with an alkaline iodine solution. But only P can react with 2,4 DNPH to produce yellow precipitate. a) Identify P & Q. Explain b) Write the chemical equations for the above reactions | |||
6 | When compound S (C4H10O) is reacted with acidified KmnO4, compound T is obtained. Reaction of S with concentrated H2SO4 yields hydrocarbon U (C4H8). Compound U reacts with dilute H2SO4 to produce compound W (C4H10O). Compound W does not react with acidified KMnO4 and its is an isomer of compound S. Determine the structural formula of S, T, U and W. | |||
7 | An ester C4H8O2 produces carboxylic acid A, C3H6O2 and alcohol B, CH4O. Alcohol B reacts with PBr3 to yield alkyl halide C. When treated with KCN followed by hydrolysis (acid), this halides produces carboxylic acid D which contain less one carbon atom than the above acid. Deduce the structures of ester, compound A, B, C & D. Write all chemical equation for the reaction involved. |
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